Aqua­chlorido{6,6′-dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methanylyl­idene)]diphenolato-κ2 O 1,N,N′,O 1′}cobalt(III) dimethyl­formamide monosolvate

摘要

In the title compound, [Co(C18H18N2O4)Cl(H2O)]·C3H7NO, the CoIII ion is six-coordinated by a tetra­dentate 6,6′-dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methanylyl­idene)]diphenolate ligand, with a chloride ion and an aqua ligand in the apical positions. The compound crystallized as a dimethyl­formamide (DMF) monosolvate. In the crystal, complex mol­ecules are linked via O—Hwater⋯O hydrogen bonds to form a dimer-like arrangement. These dimers are linked via a C—H⋯Cl inter­action, and the DMF mol­ecule is linked to the complex mol­ecule by C—H⋯O inter­actions.